Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts 
for catalytic C—O bond cleavage reactions of lignin model compounds

vom Stein, Thorsten; Weigang, Tobias; Merkens, Carina; Klankermayer, Jürgen; Leitner, Walter

doi:10.1002/cctc.201200215

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds

MPS-Authors

/persons/resource/persons58749

Leitner, Walter
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

cctc_201200215_sm_miscellaneous_information.pdf
(付録資料), 182KB

引用

vom Stein, T., Weigang, T., Merkens, C., Klankermayer, J., & Leitner, W. (2013). Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds. ChemCatChem, 5(2), 439-441. doi:10.1002/cctc.201200215.

引用: https://hdl.handle.net/11858/00-001M-0000-0014-A29E-8

要旨

Ru ready for it yet? The reaction of [Ru(cod)(methallyl)₂] with tripodal phosphine ligands of the TRIPHOS-type results in the formation of Ru-trimethylenemethane complexes. Evaluation of their catalytic properties revealed a high activity for hydrogen transfer and C—O cleavage reactions including the hydrogen-free reductive cleavage of 2-aryloxy-1-arylethanols as model compounds for lignin linkages.