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Catalytic Asymmetric Benzidine Rearrangement

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De,  Chandra Kanta
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pesciaioli,  Fabio
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

De, C. K., Pesciaioli, F., & List, B. (2013). Catalytic Asymmetric Benzidine Rearrangement. Angewandte Chemie International Edition, 52(35), 9293-9295. doi:10.1002/anie.201304039.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-C9F4-8
Abstract
A chiral Brønsted acid catalyzes the asymmetric benzidine rearrangement of N,N′‐dinaphthylhydrazines. Different electronically and structurally diverse axially chiral 2,2′‐binaphthyl diamine (BINAM) derivatives are obtained with high enantioselectivity.