English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route

MPS-Authors
/persons/resource/persons58425

Benson,  Stefan
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58492

Collin,  Marie-Pierre
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58400

Arlt,  Alexander
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58558

Gabor,  Barbara
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58578

Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58380

Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)

anie_201103270_sm_miscellaneous_information.pdf
(Supplementary material), 3MB

Citation

Benson, S., Collin, M.-P., Arlt, A., Gabor, B., Goddard, R., & Fürstner, A. (2011). Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route. Angewandte Chemie International Edition, 50(37), 8739-8744. doi:10.1002/anie.201103270.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-CA40-1
Abstract
Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring closure, yet it has allowed the power of catalytic alkyne scission and activation to be showcased. An improved strategy for the introduction of the labile side chain was also developed.