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Journal Article

Catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)].

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

Fulltext (public)

1857929.pdf
(Publisher version), 571KB

Supplementary Material (public)

1857929_Suppl_1.html
(Supplementary material), 117KB

Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]. Acta Crystallographica E, 68(7): m1018-m1019. doi:10.1107/S1600536812029285.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-B664-3
Abstract
The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex molecule of formula [Cu2(C18H14Br4N2O2)2]n. One of the CuII ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu-O bond [2.885 (4) Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. [pi]-[pi] stacking interactions [centroid-centroid distance = 3.783 (4) Å] and short interchain Br...Br interactions [3.6142 (12)-3.6797 (12) Å] are observed.