{4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II).

Kargar, H.; Kia, R.; Shakarami, T.; Tahir, M. N.

doi:10.1107/S1600536812024944

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{4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II).

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Kia, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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http://journals.iucr.org/e/issues/2012/07/00/su2444/su2444.pdf
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Citation

Kargar, H., Kia, R., Shakarami, T., & Tahir, M. N. (2012). {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II). Acta Crystallographica E, 68(7): m935. doi:10.1107/S1600536812024944.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-B67E-B

Abstract

The asymmetric unit of the title compound, [Ni(C19H16I4N2O2)], comprises half of a Schiff base complex. The NiII atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the NiII atom is distorted square-planar, with a dihedral angle of 21.7 (3)° between the symmetry-related N/Ni/O coordination planes. The dihedral angle between the symmetry-related benzene rings is 27.9 (3)°. In the crystal, short intermolecular I...I [3.8178 (9) and 3.9013 (10) Å] interactions are present.