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Journal Article

Aqua{4,4',6,6'-tetrachloro-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc.

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

Fulltext (public)

1858397.pdf
(Publisher version), 490KB

Supplementary Material (public)

1858397_Suppl_1.html
(Supplementary material), 110KB

Citation

Kargar, H., Kia, R., Abbasian, S., & Tahir, M. N. (2012). Aqua{4,4',6,6'-tetrachloro-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc. Acta Crystallographica E, 68(7), m936-m937. doi:10.1107/S1600536812025986.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-B878-7
Abstract
The asymmetric unit of the title compound, [Zn(C19H16Cl4N2O2)(H2O)], comprises two crystallographically independent molecules. The geometry around the ZnII atoms is distorted trigonal-bipyramidal, supported by the N2O2 donor atoms of the tetradentate Schiff base and a coordinating water molecule. The dihedral angles between the benzene rings in the two molecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent molecules are linked by pairs of O-H...O hydrogen bonds, forming dimers with R22(6) ring motifs, and by O-H...Cl hydrogen bonds. There are short Cl...Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and molecules are also linked by C-H...O and [pi]-[pi] [centroid-centroid distance = 3.671 (2) Å] interactions.