Synthesis of deuterium labeled polyunsaturated fatty acids

Svatoš, Aleš; Attygalle, Athula B.; Meinwald, Jerrold

doi:10.1016/0040-4039(94)88495-1

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Synthesis of deuterium labeled polyunsaturated fatty acids

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Svatoš, A., Attygalle, A. B., & Meinwald, J. (1994). Synthesis of deuterium labeled polyunsaturated fatty acids. Tetrahedron Letters, 35(51), 9497-9500. doi:10.1016/0040-4039(94)88495-1.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-0E2E-8

Abstract

Compounds containing carbon-carbon double bonds bearing cis deuterium atoms can be prepared conveniently by treating disubstituted acetylenes with bis(2-deuteriocyclohexyl)borane-B-D-1 [DB(Cy)(2)] followed by reaction with CH3CO2D. As an example, the preparation of labeled linolenic acid is reported.