Synthesis, characterization and luminescent properties of needle-like 
lanthanide-doped orthorhombic Y5O4F7

Liu, B. Q.; Liu, L. S.; Guo, K.; Wang, J.; Zhu, L. L.; Zhang, H.; Wen, W.; Yang, T. Y.; Zhao, J. T.

doi:10.1016/S1002-0721(12)60352-4

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Synthesis, characterization and luminescent properties of needle-like lanthanide-doped orthorhombic Y₅O₄F₇

MPS-Authors

/persons/resource/persons126634

Guo, K.
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126929

Zhang, H.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Liu, B. Q., Liu, L. S., Guo, K., Wang, J., Zhu, L. L., Zhang, H., et al. (2013). Synthesis, characterization and luminescent properties of needle-like lanthanide-doped orthorhombic Y₅O₄F₇. Journal of Rare Earths, 31(8), 745-749. doi:10.1016/S1002-0721(12)60352-4.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-1E6C-E

Abstract

Thermal annealing of YOH1.1F1.9 and YOH1.1F1.9:Ln(3+) (Ln(3+)=Eu3+, Tb3+ and Gd3+) precursors in air gave access to synthesize yttrium oxyfluoride phosphors with well-preserved needle-like morphologies. The phase purities of samples strongly depended on the thermal annealing temperature. At 600 degrees C, pure Y5O4F7 with orthorhombic structure were obtained, as evidenced by powder X-ray diffraction measurement and chemical analysis. The interesting microstructure evolution. of the annealed sample from well-organized nanoparticles on curly slices to microrod-bundle structure had been aroused by raising annealing temperature. The multicolor fluorescent emissions of Y5O4F7:Ln(3+) phosphors were observed, e.g. ultraviolet emission for Gd3+, green emission for Tb3+ and red emission for Eu3+, which resulted from characteristic transitions of different lanthanide ions.