Synthesis, crystal structure, and atomic interactions in NbGePt

Ackerbauer, S.-V.; Borrmann, H.; Leithe-Jasper, A.; Grin, Y.

doi:10.1007/s00706-012-0741-5

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Synthesis, crystal structure, and atomic interactions in NbGePt

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Ackerbauer, S.-V.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Borrmann, H.
Horst Borrmann, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Leithe-Jasper, A.
Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Grin, Y.
Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Ackerbauer, S.-V., Borrmann, H., Leithe-Jasper, A., & Grin, Y. (2012). Synthesis, crystal structure, and atomic interactions in NbGePt. Monatshefte für Chemie, 143(9), 1315-1319. doi:10.1007/s00706-012-0741-5.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-2132-8

Abstract

- Abstract The new ternary compound NbGePt was prepared by direct reaction of the elements. The crystal structure was investigated by single-crystal X-ray diffraction methods: structure type TiNiSi, Pearson symbol oP 12, space group Pnma , a = 6.4487(3) Å, b = 3.9300(2) Å, c = 7.5065(4) Å, Z = 4. Analysis of chemical bonding by the electron density/electron localizability approach revealed, beside the expected Ge–Pt bonds, strong covalent interactions between Nb and Ge. Graphical abstract