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Synthesis and Crystal Structure of KSc(HPO4)2

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Menezes,  P. W.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Hoffmann,  S.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Prots,  Y.
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kniep,  R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Menezes, P. W., Hoffmann, S., Prots, Y., & Kniep, R. (2009). Synthesis and Crystal Structure of KSc(HPO4)2. Zeitschrift für Anorganische und Allgemeine Chemie, 635, 33-35. doi:10.1002/zaac.200800395.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0015-259C-7
Abstract
KSc(HPO4)(2) was obtained by hydrothermal synthesis. The crystal structure was determined from single-crystal X-ray data: orthorhombic. space group Pnma (No. 62), a = 14.5095(10). b = 5.4260(4). c = 8.4882(5) angstrom, V = 668.26(8) angstrom(3) and Z = 4. The crystal structure of KSc(HPO4)(2) represents a new structure type containing twelve- and four-membered rings forming channels along [010] built of alternating ScO6 octahedra and HPO42- groups. Potassium ions reside within the twelve membered ring channels.