English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Synthesis and Crystal Structure of KSc(HPO4)2

MPS-Authors
/persons/resource/persons126751

Menezes,  P. W.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126656

Hoffmann,  S.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126806

Prots,  Y.
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126692

Kniep,  R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Menezes, P. W., Hoffmann, S., Prots, Y., & Kniep, R. (2009). Synthesis and Crystal Structure of KSc(HPO4)2. Zeitschrift für Anorganische und Allgemeine Chemie, 635, 33-35. doi:10.1002/zaac.200800395.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-259C-7
Abstract
KSc(HPO4)(2) was obtained by hydrothermal synthesis. The crystal structure was determined from single-crystal X-ray data: orthorhombic. space group Pnma (No. 62), a = 14.5095(10). b = 5.4260(4). c = 8.4882(5) angstrom, V = 668.26(8) angstrom(3) and Z = 4. The crystal structure of KSc(HPO4)(2) represents a new structure type containing twelve- and four-membered rings forming channels along [010] built of alternating ScO6 octahedra and HPO42- groups. Potassium ions reside within the twelve membered ring channels.