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[C10N2H10][ZnCl(HPO4)]2: A New Templated Zincophosphate Containing Tetrahedral Nets with 63 Topology

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Natarajan,  S.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Ewald,  B.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Prots,  Y.
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kniep,  R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Natarajan, S., Ewald, B., Prots, Y., & Kniep, R. (2005). [C10N2H10][ZnCl(HPO4)]2: A New Templated Zincophosphate Containing Tetrahedral Nets with 63 Topology. Zeitschrift für anorganische und allgemeine Chemie, 631(9), 1622-1626. doi:10.1002/zaac.200500062.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-2C7F-4
Abstract
The crystal structure of [C10N2H10][ZnCl(HPO4)]2 contains corrugated tetrahedral layers equation image with 63 topology. Charge balance is achieved by insertion of diprotonated 4,4′-bipyridine between the layers. Crystal data: monoclinic, P21/n (no. 14), a = 4.8832(2) Å, b = 22.673(2) Å, c = 8.1643(4) Å, β = 104.02(1)°; V = 877.0(1) Å3; Z = 4; R1 = 0.041 and wR2 = 0.088 for 1836 reflections [I > 2σ(I)]. Tetrahedral layers equation image are also observed in other organo-ammonium templated compounds. However, their topologies are characterized by 4.82 nets. With the title compound a layered tetrahedral net equation image with 63-topology is reported for the first time.