Phosphorus-31 MAS NMR investigations of pyridine stabilized 
dithiomonometaphosphoryl halides

Rabis, A.; Grimmer, A.-R.; Thomas, B.; Brendler, E.; Beck, S.; Meisel, M.

doi:10.1016/j.ssnmr.2005.06.001

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Phosphorus-31 MAS NMR investigations of pyridine stabilized dithiomonometaphosphoryl halides

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Rabis, A.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Rabis, A., Grimmer, A.-R., Thomas, B., Brendler, E., Beck, S., & Meisel, M. (2005). Phosphorus-31 MAS NMR investigations of pyridine stabilized dithiomonometaphosphoryl halides. Solid State Nuclear Magnetic Resonance, 28(1), 57-63. doi:10.1016/j.ssnmr.2005.06.001.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-2C8D-6

Abstract

Phosphorus-31 magic-angle spinning NMR spectroscopy was chosen in order to study a series of N-donor stabilized dithiomonometaphosphoryl halides (F, Cl, and Br) and to extract structural and bonding information from their spectra. Additionally, an unusual line splitting was observed in the 31P MAS NMR spectra of pyridine dithiomonometaphosphoryl chloride (Py→PS2Cl) and the analogous bromide (Py→PS2Br). It is shown that this effect is due to a residual dipolar coupling between phosphorus and chlorine or bromine, respectively. This work is to our knowledge the first observation of this effect between P and Br in 31P MAS NMR spectra.