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Zum chemischen Transport und zur Kristallstruktur von Seltenerdarsenaten(V)

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Schmidt,  M.
Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Müller,  U.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Cardoso Gil,  R.
Raul Cardoso, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Schmidt, M., Müller, U., Cardoso Gil, R., Milke, E., & Binnewies, M. (2005). Zum chemischen Transport und zur Kristallstruktur von Seltenerdarsenaten(V). Zeitschrift für anorganische und allgemeine Chemie, 631(6-7), 1154-1162. doi:10.1002/zaac.200400544.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-2CB1-1
Abstract
Crystals of a series of rare-earth arsenates(V) REAsO4 (RE = Sc, Y, La–Nd, Sm–Lu) and mixed crystals of selected composition were obtained by endothermic chemical transport with TeCl4 as a transport medium. The gaseous phase of the transport reaction has been studied using mass spectrometry. The crystal structures of LaAsO4 and NdAsO4 (space group: P21/n (No. 14); Pearson symbol: mP24) as well as of HoAsO4 and ScAsO4 (space group: I41/amd (No. 141); Pearson symbol: tI24) were refined from single crystal X-ray diffraction data.