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Inelastic Neutron Scattering Spectroscopy of Diazenides: Detection of the N=N Stretch

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Auffermann,  G.
Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Prots,  Y.
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kniep,  R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Auffermann, G., Prots, Y., Kniep, R., Parker, S. F., & Bennington, S. M. (2002). Inelastic Neutron Scattering Spectroscopy of Diazenides: Detection of the N=N Stretch. ChemPhysChem, 3(9), 815-817. doi:10.1002/1439-7641(20020916)3:9<815:AID-CPHC815>3.0.CO;2-1.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0015-3101-6
Abstract
Birds in a cage: The highly absorbent nitrogen-rich compounds SrN and SrN2 hide their secrets from Raman scattering experiments, but when observed using inelastic neutron scattering, the dinitrogen can be shown to lie trapped within a cage of strontium atoms. Such a structure is shown in the graphic for SrN2, in which the dumbbell-shaped dinitrogen can be clearly identified.