Sr2(OLi2Sr4)[CrN4]2, ein Nitridochromat(VI)-Oxid mit Sauerstoff in 
tetragonal-bipyramidaler Koordination durch Lithium und Strontium

Hochrein, O.; Kniep, R.

doi:10.1002/1521-3749(200201)628:1<1::AID-ZAAC1>3.0.CO;2-F

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Sr₂(OLi₂Sr₄)[CrN₄]₂, ein Nitridochromat(VI)-Oxid mit Sauerstoff in tetragonal-bipyramidaler Koordination durch Lithium und Strontium

MPS-Authors

/persons/resource/persons126655

Hochrein, O.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126692

Kniep, R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Hochrein, O., & Kniep, R. (2002). Sr₂(OLi₂Sr₄)[CrN₄]₂, ein Nitridochromat(VI)-Oxid mit Sauerstoff in tetragonal-bipyramidaler Koordination durch Lithium und Strontium. Zeitschrift für Anorganische und Allgemeine Chemie, 628(1), 1-3. doi:10.1002/1521-3749(200201)628:1<1:AID-ZAAC1>3.0.CO;2-F.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0015-31B7-E

Abstract

Green gleaming crystals of Sr-2(OLi2Sr4)[CrN4](2) were prepared by reaction of Li, Sr and CrN/Cr2N (approximate 1:1 mixture) with flowing nitrogen at 900degreesC (molar overall composition Li:Sr:Cr=6:1:similar to3). The oxygen content results from a leak in the gas supply. The crystal structure was determined by single crystal methods (triclinic; P(1) over bar; a = 615.87(9) pm, b = 682.50(10) pm, c = 754.30(8) pm, alpha = 82.302(14)degrees, beta = 75.197(10)degrees, gamma = 70.133(13)degrees; Z = 1) and contains distorted tetragonal biyramids (OLi2Sr4)(8+) and [(CrN4)-N-VI](6-)-tetrahedra besides Sr-2+.