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Journal Article

Hidden flexibility of strychnine.

MPS-Authors
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Schmidt,  M.
Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society;

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Reinscheid,  F.
Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society;

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Sun,  H.
Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society;

/persons/resource/persons15699

Reinscheid,  U. M.
Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society;

External Resource

http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201301760/pdf
(Publisher version)

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Supplementary Material (public)

1949845_Suppl.pdf
(Supplementary material), 549KB

Citation

Schmidt, M., Reinscheid, F., Sun, H., Abromeit, H., Scriba, G. K. E., Soennichsen, F. D., et al. (2014). Hidden flexibility of strychnine. European Journal of Organic Chemistry, 2014(6), 1147-1150. doi:10.1002/ejoc.201301760.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0017-BF53-8
Abstract
The prototypic molecule for conformational rigidity, that is, strychnine, exhibits fast conformational exchange on the NMR timescale at room temperature. A comprehensive description of this up-to-now-hidden stereodynamic behavior is presented, which combines experimental and computational data.