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Tl2Au4S3: x = 4/3 member of the series A2-xAuxQ. Preparation and an analysis of its gold-gold bonding

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Löken, S., Felser, C., & Tremel, W. (1998). Tl2Au4S3: x = 4/3 member of the series A2-xAuxQ. Preparation and an analysis of its gold-gold bonding. Chemical Communications, (15), 1603-1604. doi:10.1039/a802571a.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0018-53D8-D
Abstract
Tl2Au4S3 was synthesized by reacting gold with reactive fluxes of Tl2S and S; its crystal structure is characterised by sheets of buckled 16-membered rings of Au and S with short Au-Au contacts between the sheets; the Au-Au bonding has been analysed through high-level band structure calculations.