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Synthesis and characterization of copper intercalated ZrTe3

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Finckh, W., Felser, C., Tremel, W., & Ouvrard, G. (1997). Synthesis and characterization of copper intercalated ZrTe3. Journal of Alloys and Compounds, 262-263, 97-100. doi:10.1016/S0925-8388(97)00336-8.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0018-60A9-1
Abstract
Electrochemical copper intercalation in ZrTe3 yields the new metallic ternary phase CuxZrTe3 with a maximum stoichiometry of x=1.9. The charge is balanced by filling the sigma* antibonding Te p bands, as monitored by XANES spectroscopy. The reaction is accompanied by an increase in the a lattice dimension of 9%. This observation is explained by theoretical calculations. (C) 1997 Elsevier Science S.A.