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Darstellung und Kristallstruktur von TlCu[CuO2] / Preparation and Crystal Structure of TlCu[CuO2]

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Citation

Adam, A., Felser-Wenz, C., Schuster, H.-U., & Hoppe, R. (1991). Darstellung und Kristallstruktur von TlCu[CuO2] / Preparation and Crystal Structure of TlCu[CuO2]. Zeitschrift für anorganische und allgemeine Chemie, 605(14), 157-162. doi:10.1002/zaac.19916050119.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0018-602B-C
Abstract
By reaction of Tl2O3 and Cu2O in a sealed copper-type TlCu[CuO2] was synthesized; the orthorhombically bodycentered crystallizing compound forms a new structure type, space group Imma (no. 74), with the lattice constants a = 552.5 pm, b = 605.2 pm, c = 896.4 pm. The Madelung Part of Lattice Energy, MAPLE, as well as Effective Coordination Numbers, ECoN, these via Mean Effective Ionic Radii, MEFIR, were calculated.