Crystal structure and magnetism of the double perovskites A2FeReO6 (A = Ca, Sr, 
Ba)

Auth, N.; Jakob, G.; Westerburg, W.; Ritter, C.; Bonn, I.; Felser, C.; Tremel, W.

doi:10.1016/j.jmmm.2003.12.484

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Crystal structure and magnetism of the double perovskites A₂FeReO₆ (A = Ca, Sr, Ba)

MPS-Authors

There are no MPG-Authors in the publication available

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Auth, N., Jakob, G., Westerburg, W., Ritter, C., Bonn, I., Felser, C., et al. (2004). Crystal structure and magnetism of the double perovskites A₂FeReO₆ (A = Ca, Sr, Ba). Journal of Magnetism and Magnetic Materials, 272-276, E607-E608. doi:10.1016/j.jmmm.2003.12.484.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0018-6120-B

Abstract

We synthesized a series of double perovskites A(2)FeReO(6) (A = Ca, Sr, Ba) with Curie temperatures above room-temperature. Neutron and X-ray diffraction analysis have been performed in order to determine the structural and (local) magnetic properties of these materials. While Ba2FeReO6 stays cubic over the whole temperature range we examined, the Sr-compound shows a tetragonal distortion of the perovskite structure which does not completely vanish up to about 520 K far above T-C. Ca2FeReO6 has a monoclinic unit cell at high temperatures. Below 400 K a phase separation in two monoclinic phases with identical cell volume is observed in neutron scattering. (C) 2004 Elsevier B.V. All rights reserved.