Challenging the Prediction of Anionogenic Ferromagnetism for Rb4O6

Winterlik, Jürgen; Fecher, Gerhard H.; Felser, Claudia; Mühle, Claus; Jansen, Martin

doi:10.1021/ja071490z

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Challenging the Prediction of Anionogenic Ferromagnetism for Rb₄O₆

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引用

Winterlik, J., Fecher, G. H., Felser, C., Mühle, C., & Jansen, M. (2007). Challenging the Prediction of Anionogenic Ferromagnetism for Rb₄O₆. Journal of the American Chemical Society, 129(22), 6990-6991. doi:10.1021/ja071490z.

引用: https://hdl.handle.net/11858/00-001M-0000-0018-8560-0

要旨

It has been suggested that Rb4O6 should be a half-metallic ferromagnet with the magnetic moment carried by the hyperoxide anions and a Curie temperature above room temperature. In the present work, magnetic measurements are presented that were performed to investigate this prediction. These measurements provide strong evidence that Rb4O6 is a magnetically frustrated system with a magnetic transition temperature of below 10 K.