Abstract
A new homologous series of intermetallic compounds containing
three-dimensional (3-d) tetrahedral frameworks of gold atoms, akin to
hexagonal diamond, have been discovered in four related Sr-Au-Al
systems: (I) hexagonal SrAl3-x,Au4+x (0.06(1) <= x <= 0.46(1), P (6)
over bar 2m, Z = 3, a = 8.633(1)-8.664(1) angstrom, c =
7.083(2)-7.107(1) angstrom); (II) orthorhombic SrAl2-yAu5+y (y <=
0.05(1); Pnma, Z = 4, a = 8.942(1) angstrom, b = 7.2320(4) angstrom, c =
9.918(1) angstrom); (III) Sr2Al2-x,Au7+z (z = 0.32(2); C2/c, Z = 4, a =
14.956(4) angstrom, b 8.564(2) angstrom, c = 8.682(1) angstrom, beta =
123.86(1)degrees); and (IV) rhombohedral Sr2Al3-wAu6+w (w approximate to
0.18(1); R (3) over barc, Z = 6, a = 8.448(1) angstrom, c = 21.735(4)
angstrom). These remarkable compounds were obtained by fusion of the
pure elements and were characterized by X-ray diffraction and electronic
structure calculations. Phase I shows a narrow phase width and adopts
the Ba3Ag14.6Al6.4-type structure; phase IV is isostructural with
Ba2Au6Zn3, whereas phases II and III represent new structure types. This
novel series can be formulated as Sr-x[M-3](1-x)Au-2, in which [M-3] (=
[Al-3] or [Al2Au]) triangles replace some Sr atoms in the hexagonal
prismatic-like cavities of the Au network. The [M-3] triangles are
either isolated or interconnected into zigzag chains or nets. According
to tight-binding electronic structure calculations, the greatest overlap
populations belong to the Al-Au bonds, whereas Au Au interactions have a
substantial nonbonding region surrounding the calculated Fermi levels.
QTAIM analysis of the electron density reveals charge transfer from Sr
to the Al-Au framework in all four systems. A study of chemical bonding
by means of the electron-localizability indicator indicates two- and
three-center interactions within the anionic Al Au framework.
