Photoinduced Electron-Transfer in Porphyrin-quinone Cyclophanes, 15. Distance 
Dependence of Photoinduced Electron-Transfer: Syntheses and Structures of 
Naphthalene-Spacered Porphyrin-Quinone Cyclophanes

Staab, Heinz A.; Feurer, Achim; Krieger, Claus; Kumar, A. Sampath

doi:10.1002/jlac.199719971121

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Photoinduced Electron-Transfer in Porphyrin-quinone Cyclophanes, 15. Distance Dependence of Photoinduced Electron-Transfer: Syntheses and Structures of Naphthalene-Spacered Porphyrin-Quinone Cyclophanes

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger, Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Staab, H. A., Feurer, A., Krieger, C., & Kumar, A. S. (1997). Photoinduced Electron-Transfer in Porphyrin-quinone Cyclophanes, 15. Distance Dependence of Photoinduced Electron-Transfer: Syntheses and Structures of Naphthalene-Spacered Porphyrin-Quinone Cyclophanes. Liebigs Annalen der Chemie, 1997(11), 2321-2336. doi:10.1002/jlac.199719971121.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-A56E-0

Abstract

Syntheses, conformational and structural analyses of porphyrin-quinone cyclophanes 2 with naphthalene-spacers are presented and the findings are compared with data for previously investigated analogous benzene-spacered compounds 1. In combination with data for the biphenylene- and anthracene-spacered porphyrin-quinone cyclophanes 3 and 4, to be published in following papers, the results reported herein allow some appraisal to be made of the distance dependences of photoinduced electron-transfer from porphyrin to quinone units.