Assignment of the quadrupolar splittings in fully deuteriated alkyl chains of 
liquid crystalline compounds. The case of 4-n-hexyloxy-4'-cyanobiphenyl

Emsley, James W.; Foord, E. K.; Gandy, P. J. F.; Turner, D. L.; Zimmermann, Herbert

doi:10.1080/02678299408036571

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Assignment of the quadrupolar splittings in fully deuteriated alkyl chains of liquid crystalline compounds. The case of 4-n-hexyloxy-4'-cyanobiphenyl

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Zimmermann, Herbert
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;

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引用

Emsley, J. W., Foord, E. K., Gandy, P. J. F., Turner, D. L., & Zimmermann, H. (1994). Assignment of the quadrupolar splittings in fully deuteriated alkyl chains of liquid crystalline compounds. The case of 4-n-hexyloxy-4'-cyanobiphenyl. Liquid Crystals, 17(3), 303-309. doi:10.1080/02678299408036571.

引用: https://hdl.handle.net/11858/00-001M-0000-0019-A953-8

要旨

There have been disagreements about the assignment of the quadrupolar splittings in the deuteriated n-hexyl chain in 4-n-hexyloxy-4′-cyanobiphenyl (6OCB); these are resolved by comparing the splittings of the deuteron resonances in the fully deuteriated chain compound with those in the material with a selectively deuteriated chain. The methods available for assigning the quadrupolar splittings in fully deuteriated chains are then applied to 6OCB and it is concluded that measurement of spin-lattice relaxation times, T 1, is the best method.