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The dication of 1,4,5,8-tetrakis(dimethylamino)naphthalene: properties, crystal structure and a comparison with the dication of 1,4-bis(dimethylamino)benzene

MPS-Authors
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Barth,  Thomas
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger,  Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Neugebauer,  Franz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Barth, T., Krieger, C., Staab, H. A., & Neugebauer, F. A. (1993). The dication of 1,4,5,8-tetrakis(dimethylamino)naphthalene: properties, crystal structure and a comparison with the dication of 1,4-bis(dimethylamino)benzene. Journal of the Chemical Society, Chemical Communications, 1(14), 1129-1131. doi:10.1039/C39930001129.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-AAF2-F
Abstract
The dication salt 4·(I3–)2 of 1,4,5,8-tetrakis(dimethylamino)naphthalene 3 is isolated and its molecular structure established by X-ray crystallographic analysis; spectral data of 4 are compared with those of the dication 2 of 1,4-bis(dimethylamino)benzene, determined in the presence of an oxidant, i.e. Br2, Ag+.