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Journal Article

1,8-Bis(diphenylamino)- and 1,8-Bis(methylphenylamino)naphthalene: molecular structure and dynamic behavior

MPS-Authors
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Rimmler,  Gösta
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger,  Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Neugebauer,  Franz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://onlinelibrary.wiley.com/doi/10.1002/cber.19921250327/epdf
(Any fulltext)

https://dx.doi.org/10.1002/cber.19921250327
(Any fulltext)

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Fulltext (public)

ChemBerichte_125_1992_723.pdf
(Any fulltext), 628KB

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Citation

Rimmler, G., Krieger, C., & Neugebauer, F. A. (1992). 1,8-Bis(diphenylamino)- and 1,8-Bis(methylphenylamino)naphthalene: molecular structure and dynamic behavior. Chemische Berichte, 125(3), 723-728. doi:10.1002/cber.19921250327.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-AB98-4
Abstract
The title compounds 2 and 3 have been synthesized from 1,8‐diaminonaphthalene. The molecular structure of 2 has been determined by X‐ray structure analysis and is discussed with regard to the arrangement of the peri‐diphenylamino substituents in the crystalline state and the steric strain in the molecule. NMR studies of 3 reveal two conformational processes. Their nature is discussed and barriers are reported.