English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

13C Anisotropic chemical shift in a single crystal of benzophenone

MPS-Authors
/persons/resource/persons123152

Kempf,  J.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons95433

Spiess,  Hans W.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93258

Haeberlen,  Ulrich
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons128263

Zimmermann,  Herbert
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;
Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society;
Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://www.sciencedirect.com/science/article/pii/000926147280318X/pdf?md5=476d8374a5ea54cb61a0edb2f3316935&pid=1-s2.0-000926147280318X-main.pdf
(Any fulltext)

https://doi.org/10.1016/0009-2614(72)80318-X
(Any fulltext)

Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Kempf, J., Spiess, H. W., Haeberlen, U., & Zimmermann, H. (1972). 13C Anisotropic chemical shift in a single crystal of benzophenone. Chemical Physics Letters, 17(1), 39-42. doi:10.1016/0009-2614(72)80318-X.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B19F-A
Abstract
The 13C resonance of the carbonyl carbon in a single crystal of benzophenone was studied by Fourier transform NMR at room temperature. Rotation patterns about the three cyrstallographic axes yielded the orientations of the major axis systems of the chemical shift tensor σ relative to the crystallographic axes for the four molecules in the unit cell. The principal elements of σ were found to be: σxx = −79 ± 4, σyy = −36 ± 4, and σzz = +94 ± 4 ppm , relative to CS2. The Z axis of the nearly axially symmetric σ tensor was found to be perpendicular to the plane spanned by the carbonyl carbon and the carbon and oxygen atoms directly bound to it.