A New Synthetic Strategy for Magnetic Metal Bis(dithiolene) Based Conductors

Mulder, Martijn J. J.; Haasnoot, Jaap G.; Stufkens, Derk J.; Tjeng, Liu Hao; Lin, Hong-Ji; Chen, Chien-Te; Reedijk, Jan

doi:10.1002/1099-0682(200212)2002:12<3083::AID-EJIC3083>3.0.CO;2-O

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A New Synthetic Strategy for Magnetic Metal Bis(dithiolene) Based Conductors

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Citation

Mulder, M. J. J., Haasnoot, J. G., Stufkens, D. J., Tjeng, L. H., Lin, H.-J., Chen, C.-T., et al. (2002). A New Synthetic Strategy for Magnetic Metal Bis(dithiolene) Based Conductors. European Journal of Inorganic Chemistry, (12), 3083-3086. doi:10.1002/1099-0682(200212)2002:12<3083:AID-EJIC3083>3.0.CO;2-O.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-1776-1

Abstract

The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.