Deutsch
 
Benutzerhandbuch Datenschutzhinweis Impressum Kontakt
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Buchkapitel

Complex Ternary Transition-Metal Hydrides and Hydridometalates

MPG-Autoren
/persons/resource/persons126525

Auffermann,  G.
Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126550

Bronger,  W.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

Externe Ressourcen
Es sind keine Externen Ressourcen verfügbar
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Auffermann, G., & Bronger, W. (2013). Complex Ternary Transition-Metal Hydrides and Hydridometalates. In J. Reedijk, & K. Poeppelmeier (Eds.), Comprehensive Inorganic Chemistry II (Second Edition) (pp. 583-599). Amsterdam: Elsevier. doi:10.1016/j.bbr.2011.03.031.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-0019-1AE4-4
Zusammenfassung
Various preparation routes led to a large number of complex ternary transition-metal hydrides and hydridometalates containing d- and f-elements, together with alkali, alkaline-earth, and rare-earth metals. Here, the parameter pressure is a crucial tool for the selective synthesis: increasing the reaction pressure leads to higher oxidation states of the transition element. The crystal structures of hydridometalates show a broad variety of different complex formations, whereby higher valence states of transition metals are favored, with alkali metal as the counterion. Moreover, the mobility of hydrogen atoms causes numerous order–disorder transitions.