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Book Chapter

Complex Ternary Transition-Metal Hydrides and Hydridometalates


Auffermann,  G.
Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;


Bronger,  W.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Auffermann, G., & Bronger, W. (2013). Complex Ternary Transition-Metal Hydrides and Hydridometalates. In J. Reedijk, & K. Poeppelmeier (Eds.), Comprehensive Inorganic Chemistry II (Second Edition): Transition elements, lanthanides and actinides (Volume 2) (pp. 583-599). Amsterdam: Elsevier. doi:10.1016/j.bbr.2011.03.031.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-1AE4-4
Various preparation routes led to a large number of complex ternary transition-metal hydrides and hydridometalates containing d- and f-elements, together with alkali, alkaline-earth, and rare-earth metals. Here, the parameter pressure is a crucial tool for the selective synthesis: increasing the reaction pressure leads to higher oxidation states of the transition element. The crystal structures of hydridometalates show a broad variety of different complex formations, whereby higher valence states of transition metals are favored, with alkali metal as the counterion. Moreover, the mobility of hydrogen atoms causes numerous order–disorder transitions.