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Journal Article

The Hexanitridodimanganate(IV) Li6Ca2[Mn2N6]: Preparation, Crystal Structure, and Chemical Bonding

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Citation

Hochrein, O., Grin, Y., & Kniep, R. (1998). The Hexanitridodimanganate(IV) Li6Ca2[Mn2N6]: Preparation, Crystal Structure, and Chemical Bonding. Angewandte Chemie International Edition, 37(11), 1582-1585. doi:0.1002/(SICI)1521-3773(19980619)37:11<1582:AID-ANIE1582>3.0.CO;2-D.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-9202-C
Abstract
Unbridged Mn2units are present in the hexanitridodimanganate(IV) ions of the title compound. This is the first example of a Mn–Mn single bond within a complex anion in which the manganese centers have the high oxidation state +4. According to ELF calculations, the Mn–Mn bond can be regarded as a two-electron, two-center bond.