English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Model Studies on Heterogeneous Catalysts at the Atomic Scale

MPS-Authors
/persons/resource/persons21524

Freund,  Hans-Joachim
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22106

Shaikhutdinov,  Shamil K.
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21916

Nilius,  Niklas
Chemical Physics, Fritz Haber Institute, Max Planck Society;

Locator
There are no locators available
Fulltext (public)

ISHHCmanuscript_final.pdf
(Any fulltext), 2MB

Supplementary Material (public)
There is no public supplementary material available
Citation

Freund, H.-J., Shaikhutdinov, S. K., & Nilius, N. (2014). Model Studies on Heterogeneous Catalysts at the Atomic Scale. Topics in Catalysis, 57(10-13), 822-832. doi:10.1007/s11244-014-0276-6.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-B543-3
Abstract
Thin single crystalline oxide films comprise perfect supports to grow nanoparticles of metals and other catalytically relevant materials. The model systems thus created can be thoroughly investigated with respect to structure and/or chemical activity applying both, the techniques of surface science under ultrahigh vacuum conditions as well as the traditional techniques applied in catalysis to study chemical kinetics under ambient conditions. We discuss here in particular the oxidation of methanol to formaldehyde on ceria supported vanadia nanoclusters as well as the effect of transition-metal dopants in single crystalline oxides, such as CaO, on the activation of molecular oxygen.