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E3Te3Hal, Mixed Valency Tellurohalides of Gallium and Indium with One-Dimensional Structural Units

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Citation

Paashaus, S., & Kniep, R. (1986). E3Te3Hal, Mixed Valency Tellurohalides of Gallium and Indium with One-Dimensional Structural Units. Angewandte Chemie International Edition, 25(8), 752-753. doi:10.1002/anie.198607521.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B5D1-5
Abstract
An element of the third main group in the oxidation states 2 and 3 is present in the compound Ga3Te3I 1equation image, which may be crystallized according to the Bridgman method. The one-dimensional, macromolecular structural element consists of GaTe3/5I tetrahedra with GaIII centers and Ga2Te6/3 units with GaII centers. Other E3Te3Hal compounds (E = Ga, In; Hal = Cl, Br, I) have also been synthesized.