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LiCaN and Li4SrN2, Derivatives of the Fluorite and Lithium Nitride Structures

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Citation

Cordier, G., Gudat, A., Kniep, R., & Rabenau, A. (1989). LiCaN and Li4SrN2, Derivatives of the Fluorite and Lithium Nitride Structures. Angewandte Chemie International Edition, 28(12), 1702-1703. doi:10.1002/anie.198917021.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-B654-6
Abstract
The list of known ternary nitrides of lithium has been extended by two through the investigation of LiCaN and Li4SrN2. In the case of LiCaN, infinitely long math image[LiN3/3] bands are joined through common nitrogen atoms with CaN4 tetrahedra to give a structural unit that can be derived directly from the fluorite structure: “Li[4]Ca[4]N[8]” [RIGHTWARDS ARROW] Li[3]Ca[4]N[1] (see illustration).