English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

LiSrN-A Three Dimensional Structural Arrangement of Corner and Edge Sharing Orthorhombic Bipyramids, NLi2/2Sr4/4

MPS-Authors
There are no MPG-Authors in the publication available
External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Cordier, G., Gudat, A., Kniep, R., & Rabenau, A. (1989). LiSrN-A Three Dimensional Structural Arrangement of Corner and Edge Sharing Orthorhombic Bipyramids, NLi2/2Sr4/4. Angewandte Chemie International Edition, 28(2), 201-202. doi:10.1002/anie.198902011.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B647-4
Abstract
The crystalline stoichiometric phase LiSrN is an isotype of the YCoC structural type, which was first determined in 1986 by X-ray powder methods. Thus, this very simple structural type is not limited to transition-metal carbides. The metal cations Li and Sr form an arrangement previously observed in the CsCl structure. The anions (inside the polyhedron) occupy the centers of opposite faces of the (compressed) cube. LiSrN contains extended chains of [LiN]2⊖, the N atoms of which achieve rhombic-pyramidal coordination by additional contacts to four Sr atoms.