Zn4FeII5(PO4)6•4H2O: Eine reduzierte und "aufgefüllte" Variante der Zn2(Zn1-xFex
)FeIII(PO4)3•2H2O-Struktur

Schmidt, R.; Kniep, R.

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Zn₄Fe^II₅(PO₄)₆•4H₂O: Eine reduzierte und "aufgefüllte" Variante der Zn₂(Zn_1-xFe_x)Fe^III(PO₄)₃•2H₂O-Struktur

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Schmidt, R., & Kniep, R. (1992). Zn₄Fe^II₅(PO₄)₆•4H₂O: Eine reduzierte und "aufgefüllte" Variante der Zn₂(Zn_1-xFe_x)Fe^III(PO₄)₃•2H₂O-Struktur. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 47(3), 445-448.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B838-9

Abstract

Single crystals of Zn4FeII5(PO4)6.4H2O were grown by hydrothermal treatment of phosphophyllite (Zn2Fe(PO4)2.4H2O) in H2O at 180-degrees-C. The crystal structure (tricl., P1BAR; a = 651.6(4) pm, b = 902.7(4) pm, c = 995.4(4) pm, a = 69.01(5)-degrees, beta = 78.19(5)-degrees, gamma = 75.33(5)-degrees; Z = 1) can be derived from the Zn2(Zn1-xFex)FeIII(PO4)3.2H2O structure by reduction of Fe(III) to Fe(II) and by filling a ,,structure hole'' with an additional Fe(II).