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Sr2Li[Fe2N3] and Ba2Li[Fe2N3]: Nitridoferrate(II) Isotypes with 1∞[(FeN3/2)2 Anions

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Citation

Höhn, P., Haag, S., Milius, W., & Kniep, R. (1991). Sr2Li[Fe2N3] and Ba2Li[Fe2N3]: Nitridoferrate(II) Isotypes with 1∞[(FeN3/2)2 Anions. Angewandte Chemie International Edition, 30(7), 831-832. doi:10.1002/anie.199108311.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-B80A-2
Abstract
A strong structural relationship exists between B2S3 and the formally isoelectronic polymeric anion aggregates of the title compounds. These consist of Fe2N2 rings linked to form chains through common exocyclic N atoms. Distorted trigonal-planar coordination is observed for the FeII centers.(In the diagram, ○ represents N and • represents Fe.)