Sr2Li[Fe2N3] and Ba2Li[Fe2N3]: Nitridoferrate(II) Isotypes with 1∞[(FeN3/2)25Θ 
Anions

Höhn, Peter; Haag, Sabine; Milius, Wolfgang; Kniep, Rüdiger

doi:10.1002/anie.199108311

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Sr₂Li[Fe₂N₃] and Ba₂Li[Fe₂N₃]: Nitridoferrate(II) Isotypes with ¹∞[(FeN_3/2)₂^5Θ Anions

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Höhn, P., Haag, S., Milius, W., & Kniep, R. (1991). Sr₂Li[Fe₂N₃] and Ba₂Li[Fe₂N₃]: Nitridoferrate(II) Isotypes with ¹∞[(FeN_3/2)₂^5Θ Anions. Angewandte Chemie International Edition, 30(7), 831-832. doi:10.1002/anie.199108311.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B80A-2

Abstract

A strong structural relationship exists between B2S3 and the formally isoelectronic polymeric anion aggregates of the title compounds. These consist of Fe2N2 rings linked to form chains through common exocyclic N atoms. Distorted trigonal-planar coordination is observed for the FeII centers.(In the diagram, ○ represents N and • represents Fe.)