English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Sr3[MnN3] und Ba3[MnN3], die ersten Nitridomanganate(III): Trigonal-planare Anionen [MnIIIN3]6-

MPS-Authors
There are no MPG-Authors in the publication available
External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Tennstedt, A., Röhr, C., & Kniep, R. (1993). Sr3[MnN3] und Ba3[MnN3], die ersten Nitridomanganate(III): Trigonal-planare Anionen [MnIIIN3]6-. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 48(6), 794-796.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B8BC-3
Abstract
Sr3[MnN3] (hexag. P 63/m (Nr. 176); a = 764.2(1) pm, c = 529.8(1) pm; Z = 2) and Ba3[MnN3] (hexag. P 63/m (Nr. 176); a = 805.0(2) pm, c = 5 58.6(1) pm; Z = 2) are isotypes of the Ba3[FeN3] crystal structure and contain trigonal-planar anions [MnN3]6- with D3h-SyMMetry (Mn-N: 174.1(13) pm/173.7(12) pm). The compounds were prepared by reaction of mixtures of Li, Sr/Ba and Mn (molar ratio 2: 1: 1) in tungsten crucibles with nitrogen (I atm) at 850-degrees-C.