Application of 61Ni Mössbauer spectroscopy to chemical problems

Jansen, N.; Walcher, D.; Gütlich, P.; Häußinger, D.; Hannebauer, B.; Kniep, R.; Lutar, K.; Schmidt, P. C.; Sellmann, D.; Žemva, B.

doi:10.1007/BF02458896

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Application of ⁶¹Ni Mössbauer spectroscopy to chemical problems

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Jansen, N., Walcher, D., Gütlich, P., Häußinger, D., Hannebauer, B., Kniep, R., et al. (1996). Application of ⁶¹Ni Mössbauer spectroscopy to chemical problems. Il Nuovo Climento D, 18(2-3), 231-235. doi:10.1007/BF02458896.

Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-BAC1-3

Abstract

Using the possibility to produce Co-61 sources at the MAinz MIcrotron, Ni-61 Mossbauer spectroscopy was applied to different kinds of chemical problems. Measurements of isomer shifts and V-zz values in some common compounds and compounds with unusual chemical bonding for comparison with band structure calculations, measurement of Ni-61 Mossbauer parameters in model compounds for hydrogenase and dehydrogenase with an active [NiS4] centre, and study of novel binary NiF3 compounds at helium temperature are presented.