Borophosphates: Hydrothermal and Microwave-Assisted Synthesis of Na5[B2P3O13]

Hauf, C.; Yilmaz, A.; Kizilyalli, M.; Kniep, R.

doi:10.1006/jssc.1998.7955

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Borophosphates: Hydrothermal and Microwave-Assisted Synthesis of Na₅[B₂P₃O₁₃]

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Hauf, C., Yilmaz, A., Kizilyalli, M., & Kniep, R. (1998). Borophosphates: Hydrothermal and Microwave-Assisted Synthesis of Na₅[B₂P₃O₁₃]. Journal of Solid State Chemistry, 140(1), 154-156. doi:10.1006/jssc.1998.7955.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-BE45-C

Abstract

Na-5[B2P3O13] was first prepared by high temperature synthesis (T-max = 780 degrees C) and was characterized by X-ray single crystal investigations recently. We have now succeeded in the hydrothermal synthesis of the compound and obtained single-phase products at 150 degrees C after 1-2 days. A microwave-assisted synthesis takes only 2 min to transform a solid mixture of berate and phosphate hydrates into the crystalline title compound. Pure Na-5[B2P3O13] melts at 747 degrees C and solidifies during cooling by formation of a homogeneous glass. (C) 1998 academic Press.