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Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes

MPS-Authors
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Cheng,  Xu
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Vellalath,  Sveekumar
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Cheng, X., Vellalath, S., Goddard, R., & List, B. (2008). Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes. Journal of the American Chemical Society, 130(47), 15786-15787. doi:10.1021/ja8071034.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0019-D590-C
Abstract
A highly enantioselective Brønsted acid catalyzed direct synthesis of cyclic aminals from aldehydes has been developed. The methodology has been applied to the first asymmetric synthesis of several antihypertensive aminal drugs including (R)-Thiabutazide