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Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

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Kumagai,  Takashi
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Čechal, J., Kley, C. S., Kumagai, T., Schramm, F., Ruben, M., Stepanow, S., et al. (2014). Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation. Chemical Communications, 50(69), 9973-9976. doi:10.1039/C4CC03723E.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0023-C429-2
Abstract
Metal coordination assemblies of the symmetric bi-functional 4,4′-di-(1,4-buta-1,3-diynyl)-benzoic acid are investigated by scanning tunnelling microscopy on metal surfaces. The formation of long-range ordered, short-range disordered and random phases depends on the competition between the convergent and divergent coordination motifs of the individual functional groups and is crucially influenced by the substrate.