English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Molecular Recognition of Primary Amines by Three-Point Binding with Boron-Containing Host Molecules.

MPS-Authors
/persons/resource/persons58919

Reetz,  Manfred T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Niemeyer,  Christof M.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58619

Hermes,  Marcus
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58578

Goddard,  Richard
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Reetz, M. T., Niemeyer, C. M., Hermes, M., & Goddard, R. (1992). Molecular Recognition of Primary Amines by Three-Point Binding with Boron-Containing Host Molecules. Angewandte Chemie, International Edition in English, 31(8), 1017-1019. doi:10.1002/anie.199210171.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0023-CA4E-4
Abstract
The reversible formation of a dative bond between the boron center (M) of the host and the N atom of the primary amine, with simultaneous formation of hydrogen bonds between the amine H atoms and two oxygen atoms (D) of the crown ether host presents a new concept in molecular recognition (depicted schematically right). The control of the degree and direction of the molecular recognition by variation of the groups R on the amine is unprecedented