Rich diversity of single-ion magnet features in the linear OCuIIIO- ion 
confined in the hexagonal channels of alkaline-earth phosphate apatites

Kazin, Pavel E.; Zykin, Mikhail A.; Schnelle, Walter; Felser, Claudia; Jansen, Martin

doi:10.1039/c4cc03966a

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Rich diversity of single-ion magnet features in the linear OCu^IIIO^- ion confined in the hexagonal channels of alkaline-earth phosphate apatites

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Schnelle, Walter
Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Felser, Claudia
Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Jansen, Martin
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Kazin, P. E., Zykin, M. A., Schnelle, W., Felser, C., & Jansen, M. (2014). Rich diversity of single-ion magnet features in the linear OCu^IIIO^- ion confined in the hexagonal channels of alkaline-earth phosphate apatites. Chemical Communications, 50(66), 9325-9328. doi:10.1039/c4cc03966a.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0023-CE7E-5

Abstract

Following our recent discovery of slow spin relaxation in the unique [(OCuO)-O-III](-) anion located in the apatite-type pigment A(10)(PO4)(6)-(CuxOH1-x-y)(2), where A = Sr, we present the magnetic behavior of this anion for the cases of A = Ca and Ba, which provides evidence for a cation field impact on the properties of a single-ion magnet molecular anion.