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Macrocycle Formation by Ring-Closing-Metathesis. 2. An Efficient Synthesis of Enantiomerically Pure (R)-(+)-Lasiodiplodin

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Kindler,  Nicole
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Kindler, N. (1996). Macrocycle Formation by Ring-Closing-Metathesis. 2. An Efficient Synthesis of Enantiomerically Pure (R)-(+)-Lasiodiplodin. Tetrahedron Letters, 37(39), 7005-7008. doi:10.1016/0040-4039(96)01590-0.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-0798-E
Abstract
A highly efficient and flexible route to the macrolide (R)-(+)-lasiodiplodin 1 and its de-Omethyl congener 2 is outlined, which is based on the formation of the 12-membered ring by ringclosing metathesis (RCM) as the key step.