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Cooperative proton-electron transfer in a supramolecular structure of meso-1,2-bis-(4-dimethylaminophenyl)-1,2-ethanediol and bis(4-cyanobenzylidene)ethylenediamine

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Felderhoff,  Michael
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Institut für Organische Chemie der Universität D-45117 Essen (Germany);

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Citation

Felderhoff, M., Steller, I., Reyes-Arellano, A., Boese, R., & Sustmann, R. (1996). Cooperative proton-electron transfer in a supramolecular structure of meso-1,2-bis-(4-dimethylaminophenyl)-1,2-ethanediol and bis(4-cyanobenzylidene)ethylenediamine. Advanced Materials, 8(5), 402-405. doi:10.1002/adma.19960080505.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-1DB3-3
Abstract
A supramolecular 1:1 complex of the title compounds undergoes light-induced cooperative proton-electron transfer which can be switched back by warming to 60°C. The complex (see Figure) is found to exhibit a unique from the photochromism, meaning that it could have potential in optical switching (with termal back switching) or optical data storage applications.