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Cationic ruthenium allenylidene complexes as a new class of performing catalysts for ring closing metathesis

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., Picquet, M., Bruneau, C., & Dixneuf, P. H. (1998). Cationic ruthenium allenylidene complexes as a new class of performing catalysts for ring closing metathesis. Chemical Communications, (12), 1315-1316. doi:10.1039/A803286F.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-5A9D-5
Abstract
Cationic allenylidene ruthenium complexes [Ru=C=C=CR2(L)(Cl)(arene)]PF6 (L = PCy3, PPri3), easily prepared from RuCl2(L)(p-cymene), prop-2-yn-1-ol and NaPF6, are found to be excellent catalyst precursors for ring closing olefin metathesis.