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学術論文

Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0):a route to L–M(alkene)2 complexes containing non-activated alkenes

MPS-Authors

Krause,  Jochen
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Haack,  Karl-Josef
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Cestaric,  Günter
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pörschke,  Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Krause, J., Haack, K.-J., Cestaric, G., Goddard, R., & Pörschke, K.-R. (1998). Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0):a route to L–M(alkene)2 complexes containing non-activated alkenes. Chemical Communications, 12, 1291-1292. doi:10.1039/a802381f.


引用: http://hdl.handle.net/11858/00-001M-0000-0024-44A3-A
要旨
With hepta-1,6-diene and diallyl ether, Pd0 and Pt0 form highly reactive homoleptic dinuclear M2(1,6-diene)3 complexes, which are cleaved by donors L (e.g. C2H4, phos-phanes, phosphites, isonitriles) to afford mononuclear derivatives L–M(1,6-diene); the X-ray structure of (Me3P)Pd{(η2-CH2=CHCH2)2O} has been determined.