Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0):a 
route to L–M(alkene)2 complexes containing non-activated alkenes

Krause, Jochen; Haack, Karl-Josef; Cestaric, Günter; Goddard, Richard; Pörschke, Klaus-Richard

doi:10.1039/a802381f

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Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0):a route to L–M(alkene)₂ complexes containing non-activated alkenes

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Krause, Jochen
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Haack, Karl-Josef
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Cestaric, Günter
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard, Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pörschke, Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Krause, J., Haack, K.-J., Cestaric, G., Goddard, R., & Pörschke, K.-R. (1998). Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0):a route to L–M(alkene)₂ complexes containing non-activated alkenes. Chemical Communications, 12, 1291-1292. doi:10.1039/a802381f.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-44A3-A

Abstract

With hepta-1,6-diene and diallyl ether, Pd⁰ and Pt⁰ form highly reactive homoleptic dinuclear M₂(1,6-diene)₃ complexes, which are cleaved by donors L (e.g. C₂H₄, phos-phanes, phosphites, isonitriles) to afford mononuclear derivatives L–M(1,6-diene); the X-ray structure of (Me₃P)Pd{(η²-CH₂=CHCH₂)₂O} has been determined.