Low-valent transition metal induced C–C-bond formations: Stoichiometric 
reactions evolving into catalytic processes

Fürstner, Alois

doi:10.1351/pac199870051071

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Low-valent transition metal induced C–C-bond formations: Stoichiometric reactions evolving into catalytic processes

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Fürstner, Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner, A. (1998). Low-valent transition metal induced C–C-bond formations: Stoichiometric reactions evolving into catalytic processes. Pure and Applied Chemistry, 70(5), 1071-1076. doi:10.1351/pac199870051071.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-20E1-7

Abstract

A new concept for C-C-bond formations catalyzed by early transition metals in low oxidation state is outlined. It allows to perform intramolecular reductive carbonyl coupling reactions catalytic in titanium, accounts for the first chromiumcatalyzed Nozaki-Hiyama-Kishi reactions, and has been successfully applied to titanium-, samarium- or vanadium-catalyzed pinacolization reactions.