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Coordinatively unsaturated ruthenium allenylidene complexes: highly effective, well defined catalysts for the ring-closure metathesis of α,ω-dienes and dienynes

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Liebl,  Monika
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., Hill, A. F., Liebl, M., & Wilton-Ely, J. D. E. T. (1999). Coordinatively unsaturated ruthenium allenylidene complexes: highly effective, well defined catalysts for the ring-closure metathesis of α,ω-dienes and dienynes. Chemical Communications, (7), 601-602. doi:10.1039/A900187E.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-21D2-1
Abstract
The well defined, conveniently accessible and coordinatively unsaturated allenylidene complexes [RuCl2(=C=C= CPh2)(PCy3)2] and [Ru2Cl4(=C=C=CPh2)(PCy3)(η-MeC6-H4Pri-4)] are highly effective catalysts for the ambient temperature ring-closure metathesis of α,ω-dienes and dienynes, illustrated by the facile and high yielding formation of variously functionalised 5, 6, 7, 8, 15, 16 and 18 membered mono- and bi-cyclic ring systems.